Minister Arseniy Yatsenyuk but no official announcement on weapons deliveries is expected.
A Ukrainian diplomatic source told AFP that Kiev was hoping to get more “clarity” on its request for weapons following Kerry’s visit and a raft of high-level meetings at an upcoming security conference in Munich.
Ukraine and its Western allies accuse Moscow of sending thousands of regular army troops and weapons to support the rebels and spearhead their latest offensive.
Moscow has repeatedly denied the allegations but the rebels, however, appear to be equipped with the heavy weaponry of a regular army.
As rebels continued to push their offensive, their leaders have announced a mass mobilisation aimed at boosting fighter numbers to 100,000.
The voluntary call-up—which has been met with scepticism by some in rebel-held territory—is set to start next Monday, insurgent leader Alexander Zakharchenko said.
Kiev authorities announced at the end of January that they also were calling up 50,000 troops in the face of the latest rebel offensive.
Hopes of defusing the conflict look more distant than ever after the latest attempt at truce talks collapsed in acrimony in the Belarussian capital Minsk over the weekend.
The rebels say they are willing to stop fighting only if Kiev agrees to redraw the demarcation line agreed in a September ceasefire deal to include gains they have made since in recent days.
In the meantime, life for civilians trapped in the crossfire continues to deteriorate rapidly, with many fleeing.
“The situation is getting worse by the day,” the head of the International Committee of the Red Cross in Ukraine, Michel Masson, said in a statement.
“People are hiding in basements for days on end and those who dare to venture out to collect basic aid risk being wounded or killed.”
Meanwhile, tens of thousands of people petitioned President Vladimir Putin Tuesday to release a mother of seven accused of treason for having called the Ukrainian embassy about Russian troop movements.
Svetlana Davydova, who faces between 12 and 20 years in prison, is being held in the high-security Lefortovo jail in Moscow.
She was still breastfeeding her youngest child, a two-and-a-half-month-old girl, when she was arrested last month in the town of Vyazma, west of Moscow.
The case has shocked the country, and prompted over 50,000 Russians—including prominent authors, directors and TV celebrities—to sign an open letter to Putin.
“Mr President, we ask you to be merciful towards a woman and mother of a large family,” the letter reads. ”We are hoping that investigation and a possible trial will be as open and just as possible and will be in accordance with the norms of the law.”
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